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Ionic Lubricants |
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Overview |
Few mechanical
systems exist today where one material does not move
relative to another. Due to this motion, a potential
exists for friction and perturbations to cause wear
and tear especially if the moving parts have been hardened
to withstand external stresses. Lubricanting oils and
greases are employed to lessen the impact of friction
and perturbations and thereby increase the useful life
of mechanical systems in addition to reducing down-time
and energy consumption.
Viscosity is arguably
the most important property of a lubricant and represents
a measure of a liquid’s resistance to flow. A
wide range of viscosities are in use today from 2.2
cSt to 3200 cSt with operating environments and application
specific considerations determining the chosen lubricant.
Lubricating oils
are used in applications with low to middle range rotational
velocities and loads. They are commonly divided into
two categories: mineral and synthetic. Mineral-based
oils are extracted from crude oil and segregated according
to similar boiling point ranges at refineries (indicative
of the hydrocarbons present). The separate distillates
are then cleaned and added together in certain proportions
to create lubricating oils with the desired viscosity.
Mineral-based oils enjoy widespread use due to their
low price, class-wide compatibility, and adequate lubricating
properties. However, mineral-based oils are environmentally
unfriendly, possess limited useful lives, and perform
adequately only within limited temperature ranges.
Synthetic lubricants,
on the other hand, are specialty chemicals engineered
to replicate the benefits of mineral-based oils without
the disadvantages. Synthetic lubricants perform better
in extreme temperature ranges (below -60°C and above
200°C) over longer lifetimes within lower tolerances.
Built upon an ionic
liquid platform, NanoTechLabs’ ionic lubricants,
developed originally in collaboration with Wake Forest
University’s Department of Chemistry, perform
well under a wide range of loads in addition to maintaining
lubricating properties over a wide temperature range.
They are: |
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- Environmentally
friendly - NanoTechLabs' ionic lubricants emit no
toxic fumes at high temperatures, and possibilities
exist to create these from renewable ingredients.
- Inflammable
- Non-volatile
through negligible vapor pressure - NanoTechLabs'
ionic lubricants will not evaporate in low pressure
environments and they do not boil.
- Capable of
operating at wider temperature ranges than competitors
(-60 C to 500 C)
- Flexible in
design to allow materials to tailored for application
environment
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Parameters and Attributes |
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[EMIM][BF4] |
[BMIM][BF4] |
[DPMI]Im |
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| Density
at 60oC |
1.3 |
1.2 |
1.4 |
| Freezing
points |
14.4 |
-87.4 |
11.3 |
| Thermal
decomposition onset |
445.5 |
423.7 |
457.0 |
| Heat
capacity at 100oC |
1.3 |
1.7 |
1.2 |
| Heat of fusion |
48.2 |
-- |
47.0 |
| Heat
storage density, sensible 100oC |
160.9 |
194.9 |
169.9 |
| Heat
storage capacity, latent |
60.4 |
-- |
66.7 |
| Vapor
pressure |
<<
1 atm |
<<
1 atm |
<<
1 atm |
| Thermal
conductivity (298K) |
0.20 |
0.19 |
0.13 |
| Viscosity
(298K) |
36.0 |
119.8 |
90.1 |
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Applications |
There are many high-performance
applications for ionic lubricants in terrestrial as well
as space environments including:
- Engine oils
- Turbine oils
- Bearing oils
- Compressor oils
- Way oils
- Chain lubricants
- Hydraulic oils
- MEMS
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